GOOD2USE Knowledge Network Send mail as another user, in such a way that the recipient can't tell.

PC Knowledge Base - Send mail as another user, in such a way that the recipient can't tell.

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Exchange/Outlook has two similar, but quite different, features:
Send on behalf of and Send As.

Send on behalf of means that the sender can send mail under the authority of another person. Outlook communicates this process by saying something like "Joe Davis on behalf of Paul Robichaux" on mail that a user sends using this option.

Send As means that when you grant an NT account Send As permission on a mailbox, the holder of that account can send mail from the mailbox that is indistinguishable from mail sent by the primary mailbox owner.

You set Send As permission in the mailbox Properties dialog box; don't forget that permission changes can take some time to propagate.

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